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The taste and flavor profile of red paprika is very different from that of red chili powder. Red chili powder has an earthy and pungent taste. It is rarely used alone, but added to other spices and condiments in any dish. Depending on the kind of red chili powder used, it brings some degree of heat to the food.

It also lacks the extra ingredients that you'll find in most blended chili powder preparations. You can substitute one for the other in some recipes, but you might need to adjust your other ingredients to account for the change in flavor.