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So, as you likely know, cayenne powder is particularly hot and spicy. As a result, it is primarily used to add heat, not flavor, to food. A little goes a long way with cayenne powder, so most recipes will call for relatively small quantities (usually 1/8-1/4 teaspoon for a whole meal).

If you want to add a nice spicy kick without all the overpowering heat, chili powder is a suitable sweet paprika substitute. Despite that, you can’t use chili powder in a 1:1 substitution because of its noticeable savory flavor that comes from a mix of other spices such as onion powder, cumin, garlic, and more. In general, it has an earthy, savory, and slightly spicy taste. But it will do if you’re in a bind or in the middle of garnishing your deviled eggs and curries. 

Origins and Varieties

While most chili powder sold in US grocery stores contains blended spices, this term can also be used for powdered hot peppers on their own. This usage is common in Asian recipes and grocery stores. These powders tend to be much spicier than blended American chili powder.