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So, as you likely know, cayenne powder is particularly hot and spicy. As a result, it is primarily used to add heat, not flavor, to food. A little goes a long way with cayenne powder, so most recipes will call for relatively small quantities (usually 1/8-1/4 teaspoon for a whole meal).

So, how do you replace hot paprika with smoked paprika? You first need to combine your smoked paprika with your chili. Here's the ratio I highly recommend: