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The sulphur trioxide formed is first made to react with concentrated sulphuric acid. Sulphur trioxide cannot be dissolved in water directly as it leads to the formation of fog. The product obtained after this reaction is known as oleum. The oleum obtained is then dissolved in water to obtain concentrated sulphuric acid.

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As a Catalyst:

Sulphur trioxide is formed when sulphur dioxide reacts with oxygen in a ratio of 1:1 at a temperature of 400 °C – 450°C and a pressure of 1-2 atm in the presence of V2O5 as a catalyst. This reaction is reversible in nature.

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