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Therefore, when zinc reaches saturation in the solid melt, the two elements of zinc and iron atoms diffuse with each other, and the zinc atoms diffused into (or infiltrated into) the iron matrix migrate in the lattice of the matrix and gradually form an alloy with iron, while the iron diffused into the molten zinc liquid forms an intermetallic compound FeZn13 with zinc and sinks into the bottom of the hot-dip galvanized pot, that is, zinc slag. When the workpiece is removed from the zinc leaching solution, the surface of the pure zinc layer is formed, which is hexagonal crystal, and its iron content is not more than 0.003%.